Hi Falko. Thanks for the response.
What I actually was looking for was this:
allback_relay (default: empty)
Optional list of relay hosts for SMTP destinations that can't be found or that are unreachable. With Postfix 2.3 this parameter is renamed to smtp_fallback_relay.
By default, mail is returned to the sender when a destination is not found, and delivery is deferred when a destination is unreachable.
The fallback relays must be SMTP destinations. Specify a domain, host, host

ort, [host]

ort, [address] or [address]

ort; the form [host] turns off MX lookups. If you specify multiple SMTP destinations, Postfix will try them in the specified order.
Note: before Postfix 2.2, do not use the fallback_relay feature when relaying mail for a backup or primary MX domain. Mail would loop between the Postfix MX host and the fallback_relay host when the final destination is unavailable.
* In main.cf specify "relay_transport = relay",
* In master.cf specify "-o fallback_relay =" (i.e., empty) at the end of the relay entry.
* In transport maps, specify "relay:nexthop..." as the right-hand side for backup or primary MX domain entries.
Postfix version 2.2 and later will not use the fallback_relay feature for destinations that it is MX host for.
However, thanks again!!!!
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