Okay, I am finally getting things setup... however, secure smtp refuses to work right now. I can use regular smtp just fine, but secure simply hangs in Evolution and won't deliver mail (no error). The mail.log file gives no indication of an attempted connection. My netstat -tap has this entry twice:
tcp6 0 0 *:ssmtp *:* LISTEN 21597/master
So it seems to me that postfix is "listening", I am just not sure on which port (assumed 465?). I am not sure what else could be the problem.