1) How did you try to access the site? Sites can be accessed by domain name only or by IP address if a site has a dedicated IP. What does not work is something like http://192.168.0.10/mydomain.com/web/
2) Enable chrooting in the client settings. And donz mix up the /etc directory that you see as chrooted user with the /etc directory of the server, these are not the same!