I would recommend to use unison instaed of glusterfs as described in the ispconfig mirror guide for debian 6. The problem that your servers dont sync is most likely related to wrong /etc/hosts file entries on the master and or slave so that the mysql client on the slave can not connect to the master anymore. If the /etc/hosts files on master and slave dont contain identical records for master and slave before you start the installation of ispconfig (and they may contain only the fqdn domain names), thn msql will fail to authenticate later and no data gets synced.
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